Prediction of liquid-liquid equilibria by an analytical solutions of groups.

Prediction of Vapor-Liquid Equilibria Using CEOS /GE Models

The present study investigates the use of different GE mixing rules in cubic equations of state for prediction of phase behavior of multicomponent hydrocarbon systems. To predict VLE data in multicomponent symmetric and asymmetric mixtures such as systems that contain light gases (nitrogen, carbon dioxide, etc.) and heavy hydrocarbons, the SRK equation of state has been combined with excess Gib...

Prediction of Liquid-Liquid Equilibria of Binary Systems Containing Alcohols Using EoS-GE Models

Modeling of liquid–liquid equilibria of aqueous alcohol + salt systems using amodified NRTL

The modified NRTL (m-NRTL) model is used to represent the excess Gibbs free energy of aqueous (alcohol + electrolyte) solutions. In this work, the m-NRTL model previously developed for representation of vapor-liquid equilibria for (polymer + salt + water) systems has been extended to represent liquid-liquid equilibria of (alcohol + salt + water) systems. The proposed extension is a modified of ...

Pressure Dependence of Liquid Vapor Pressure: An Improved Gibbs Prediction

A new model for the vapor phase of a pressurized liquid called "the cluster model: which is originally introduced in this work, along with an accurate equation of state for the liquid phase called the LIR, is used to derive an accurate equation for the vapor pressure of liquid as a function of external pressure. The chemical Potential of both phase have been found to be in good agreement wi...

Analytical applications of liquid-liquid phase equilibria: analysis of binary mixtures of chemically similar components.

A new, simple and rapid method based on the principle of liquid-liquid phase equilibria has been developed for the analysis of binary mixtures of chemically similar organic compounds. The method does not require elaborate instrumentation and can be used to analyse mixtures of members of homologous series. The application of the method has been illustrated by analysing binary mixtures of n-hexan...